Ag⼀Ag 和Ag⼀AgCl标准电极电位有区别吗?怎么进行转换呢?求解

2025-04-05 14:49:54
推荐回答(1个)
回答1:

(1)Ag/Ag+ 和Ag/AgCl标准电极电位有区别!
(2) E ==E0 + 0.059lg1/[Ag+]
(3) [Ag+][CI-] == Ksp
[Ag+] == Ksp/[CI-]
(4)E ==E0 + 0.059lg[CI-]/Ksp
[CI-] ==1mol/L
EAg/AgCI^ 0 ==EAg/Ag+^ 0 + 0.059lg1/Ksp