HAc浓度Ca,NaAc浓度Cb物料守恒[Na+]=Ca,[HAc]+[Ac-]=Ca+Cb电荷守恒[Na+]+[H+]=[Ac-]+[OH-]联立[Ac-]=Cb+[H+]-[OH][HAc]=Ca-[H+]+[OH-]带入HAc的Ka计算式[H+]=Ka[HAc]/[Ac-]=Ka(Ca-[H+]+[OH-]) / Cb+[H+]-[OH]简化[H+]=kaCa/Cb,Ca=Cb,[H+]=KaPH=PKa=4.75